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CO2 Cascade System Applied To Low Temperature Process System
Cascade systems are used for very low temperature applications. They cascade heat rejection from the low temperature refrigerant to the high temperature refrigerant through a cascade condenser. At normal condensing temperatures, low temperature refrigerants usually have high coincidental (saturated) pressures ... the temperature level required to reject the entire refrigeration system heat to ambient.
Refrigerant Choices: Why Does It Matter?
Typical low temperature refrigerants have a very low specific volume. This means a much smaller compressor can be installed than when refrigerants such as R-22 or ammonia are used at very low temperatures.

Issues related to ODP (Ozone Depletion Potential) and GWP (Global Warming Potential) have eliminated some traditional halocarbon refrigerants such as R503 and R13 and made the remaining choice, R23, prohibitively expensive.

Hydrocarbons such as ethane and ethylene have the advantage of low specific volume and cost, but they are class A3 refrigerants with high flammability.
CO2 is a very effective low temperature cascade refrigerant
CO2 is very low in cost with excellent thermodynamic properties at low temperature, including a low specific volume that allows for much smaller compression hardware. Most important, it is environmentally benign, allowing you to eliminate the costly expansion tank associated with traditional cascade refrigerants.
Installation
YORK Process Systems recently started up a -49°F CO2 cascade system at a petrochemical plant in Mobile, Alabama. The system was commissioned smoothly and successfully, and now provides the plant its desired capacity and temperature. The plant chose the refrigerant on the basis of smaller low stage compressor costs, the environmental compatibility of CO2, and the availability and low replacement cost compared to traditional halocarbon refrigerants.

The user is a multifaceted petrochemical complex producing many chemical intermediates used in adhesives, solvents, cleaning agents and a number of consumer products. The unit has been running very successfully for six months and a second unit has recently been shipped to the same job site. This is the sixth unit of this type built by YORK Process Systems in the US for the petrochemical market. The unit is a 150-ton CO2/R22 package. It uses two Frick screw compressors at 250HP and 400HP cooling d-Limonene in a flooded evaporator to -49°F. The high stage R22 compressor was selected for future conversion to R507.

Both the CO2 and high stage compressor are factory standard rotary screw compressors. The CO2 requires no special materials as long as the refrigerant is dry and operating within the temperature parameters described. Screw compressors are uniquely adaptable to these refrigerant options since they are positive displacement, high flow compressors that can easily adjust to variations in pressure rise and capacity.
Low cost, smaller compressors, high efficiency, elimination of an expansion tank and zero ODP make CO2 a preferred choice for low temperature refrigeration applications.